Singh, Parvinder Pal and Gudup, Satish and Ambala, Srinivas and Singh, Umed and Dadhwal, Sumit and Singh, Baldev and Sawant, Sanghapal D. and Vishwakarma, Ram A. (2011) Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers. Chemical Communications, 47 (20). p. 5852. ISSN 1359-7345

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We report a new and efficient iron oxide catalyzed crosscoupling reaction between organometallic species such as alkyl/arylmagnesium halides or organolithium species and a-hydrogen bearing cyclic aliphatic ethers via activation of C(sp3)–H. This is the first example of iron oxide mediated direct C–C bond formation without expensive or toxic ligands.

Item Type: Article
Subjects: Chemical Sciences
Depositing User: Mr. Amit Nargotra
Date Deposited: 28 Dec 2011 11:32
Last Modified: 28 Dec 2011 11:32

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